Late 90’s - the little “riding man” on the top tube showed up in ‘97 or 98. Before that it was the clover leaf on the top tube. My guess is Tecnos. Those have round seat tubes. I think Masters have a shaped seat tube.
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N = '96 Colnago C40, '04 Wilier Alpe D'Huez, '10 Colnago EPS, '85 Merckx Pro, '89 Merckx Century, '86 Tommasini Professional, '04 Teschner Aero FX Pro, '05 Alan Carbon Cross, '86 De Rosa Professional, '82 Colnago Super, '95 Gios Compact Pro, '95 Carrera Zeus, '84 Basso Gap, ‘89 Cinelli Supercorsa, ‘83 Bianchi Specialissima, ‘VO Randonneur, Ritchey Breakaway Steel, '84 Paletti Super Prestige, Heron Randonneur