Which anti-seize for titanium frame?
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Just a followup, a little over 4 years later, and after about 7,000 miles. I replaced the bottom bracket again. I have ridden in some very wet muddy conditions, The old BB took quite a bit of arm muscle to get out using a 14 inch long wrench, but it did come out. It was kind of dry, no lube apparent in the threads, and I do remember liberally greasing that thing up before the install.
The question you asked above as to why more people aren't using it? I don't know except not everyone knows about it, knows how to apply it or has it on hand. There have been other posters on this forum over the years that have mentioned using it so I'm far from the only one.
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But you say it seemed to go away when you took it apart 4 years later. Bet you a buck that marine grease will look the same as when you assembled it. Marine grease is formulated for a much harsher world than any bike ever sees. Think about it. The stuff has to hold up 4' deep in salt water, get pulled out wet and protect a bearing10 minutes later at highway speed. On another day, dumped still warm back into the salt water.
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Titanium and antiseize is misunderstood.
On hot, high friction uses, titanium can gall from its contact with other metals - usually Ti or steel. Galling is best addressed with copper antiseize. Bikes do not suffer from galling.
Titanium (and carbon) is on the other end of the galvanic reaction scale from aluminum. Ride in the wet and a circuit is formed that causes the aluminum to form an oxide, causing it to expand as white brittle stuff. I've pulled aluminum cups out of Ti frames that crumbled on the tops of the threads. The Ti was untouched. Nothing really wrong with teflon tape, but it generally does not electrically isolate anything because the threads cut through it.
I think the very best antiseize would address the galvanic corrosion issue by offering a 'sacrificial anode' that is even more reactive than the aluminum - like magnesium or zinc. If not, the standard antiseize contains aluminum, which is at least more reactive than copper.
On hot, high friction uses, titanium can gall from its contact with other metals - usually Ti or steel. Galling is best addressed with copper antiseize. Bikes do not suffer from galling.
Titanium (and carbon) is on the other end of the galvanic reaction scale from aluminum. Ride in the wet and a circuit is formed that causes the aluminum to form an oxide, causing it to expand as white brittle stuff. I've pulled aluminum cups out of Ti frames that crumbled on the tops of the threads. The Ti was untouched. Nothing really wrong with teflon tape, but it generally does not electrically isolate anything because the threads cut through it.
I think the very best antiseize would address the galvanic corrosion issue by offering a 'sacrificial anode' that is even more reactive than the aluminum - like magnesium or zinc. If not, the standard antiseize contains aluminum, which is at least more reactive than copper.
#29
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But you say it seemed to go away when you took it apart 4 years later. Bet you a buck that marine grease will look the same as when you assembled it. Marine grease is formulated for a much harsher world than any bike ever sees. Think about it. The stuff has to hold up 4' deep in salt water, get pulled out wet and protect a bearing10 minutes later at highway speed. On another day, dumped still warm back into the salt water.
Quote me in 4 years and tell me I'm wrong if I am. I'll be here.
Quote me in 4 years and tell me I'm wrong if I am. I'll be here.
#30
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Titanium and antiseize is misunderstood.
On hot, high friction uses, titanium can gall from its contact with other metals - usually Ti or steel. Galling is best addressed with copper antiseize. Bikes do not suffer from galling.
Titanium (and carbon) is on the other end of the galvanic reaction scale from aluminum. Ride in the wet and a circuit is formed that causes the aluminum to form an oxide, causing it to expand as white brittle stuff. I've pulled aluminum cups out of Ti frames that crumbled on the tops of the threads. The Ti was untouched. Nothing really wrong with teflon tape, but it generally does not electrically isolate anything because the threads cut through it.
I think the very best antiseize would address the galvanic corrosion issue by offering a 'sacrificial anode' that is even more reactive than the aluminum - like magnesium or zinc. If not, the standard antiseize contains aluminum, which is at least more reactive than copper.
On hot, high friction uses, titanium can gall from its contact with other metals - usually Ti or steel. Galling is best addressed with copper antiseize. Bikes do not suffer from galling.
Titanium (and carbon) is on the other end of the galvanic reaction scale from aluminum. Ride in the wet and a circuit is formed that causes the aluminum to form an oxide, causing it to expand as white brittle stuff. I've pulled aluminum cups out of Ti frames that crumbled on the tops of the threads. The Ti was untouched. Nothing really wrong with teflon tape, but it generally does not electrically isolate anything because the threads cut through it.
I think the very best antiseize would address the galvanic corrosion issue by offering a 'sacrificial anode' that is even more reactive than the aluminum - like magnesium or zinc. If not, the standard antiseize contains aluminum, which is at least more reactive than copper.
Milk of Magnesia as Anti-Sieze? - The Home Machinist!
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How about Milk of Magnesia?
Milk of Magnesia as Anti-Sieze? - The Home Machinist!
Milk of Magnesia as Anti-Sieze? - The Home Machinist!
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A: A Phillips Screwdriver!
Back on topic: When I got my Airborne 20+ years ago, I added a titanium seatpost. The bike was shipped with a little tube of Finish Line Copper Assembly Lube. I've renewed the grease 3 or 4 times over the years and have had no issues with the seatpost sticking to the frame.
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Copper based antiseize is what Lynskey recommends for Ti threads.
#34
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How about Milk of Magnesia?
Milk of Magnesia as Anti-Sieze? - The Home Machinist!
Milk of Magnesia as Anti-Sieze? - The Home Machinist!
But remember it is used in hot sections and will not work in cold areas, especially if exposed to water. Use caution and the correct anti-seize compound required for the job you are doing.
Last edited by Hondo6; 04-15-23 at 06:56 AM.
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I was always brought up to service the brakes on my car with copper grease, but a spell living next to the North Sea on the Moray Firth, and I mean next to it, seized everything with the word brake on my car. So I used ceramic grease
I also do my hardest to use eco products, eco grease and oils are all I use. I admit I have to look deeper into the claims of ceramic grease manufacturers, I just have a little pot left over from the car and it has just been very economical, and once I have used it I will write to the manufacturers asking for their green policy. I know, I know, claiming green and have a car, get public transport integrated world government's please, and of course I use my bike as much as I can!
Sorry, quick rant on PTFE/Teflon/polytetrafluoroethylene/polymer fume fever/Teflon Toxicosis look them up, are very bad environmentally, and to your health. https://www.ewg.org/research/canaries-kitchen
Some cut and paste from on line sellers below.
”Ceramic Grease does not contain metal, it is not conductive.
Ceramic Grease is free of silicones and metal, as a result of which the product meets the environmental regulations on the use of heavy metals. Thanks to its ceramic particles the product has a superior pressure and temperature resistance range. The ceramic particles remain intact above the decomposition temperature of the grease and the mineral oils.
Ceramic Grease is also extremely well suited to greasing nuts and bolts during disassembly. It does not become brittle in high temperatures and its very good resistance to water and acids gives it rust prevention characteristics, thereby guaranteeing good protection against the effects of dirt and moisture. When Ceramic Grease is used, nuts and bolts are much easier to free afterwards.
Because the product is metal-free it also works as an insulator between different metals, thereby preventing corrosion.”
I also do my hardest to use eco products, eco grease and oils are all I use. I admit I have to look deeper into the claims of ceramic grease manufacturers, I just have a little pot left over from the car and it has just been very economical, and once I have used it I will write to the manufacturers asking for their green policy. I know, I know, claiming green and have a car, get public transport integrated world government's please, and of course I use my bike as much as I can!
Sorry, quick rant on PTFE/Teflon/polytetrafluoroethylene/polymer fume fever/Teflon Toxicosis look them up, are very bad environmentally, and to your health. https://www.ewg.org/research/canaries-kitchen
Some cut and paste from on line sellers below.
”Ceramic Grease does not contain metal, it is not conductive.
Ceramic Grease is free of silicones and metal, as a result of which the product meets the environmental regulations on the use of heavy metals. Thanks to its ceramic particles the product has a superior pressure and temperature resistance range. The ceramic particles remain intact above the decomposition temperature of the grease and the mineral oils.
Ceramic Grease is also extremely well suited to greasing nuts and bolts during disassembly. It does not become brittle in high temperatures and its very good resistance to water and acids gives it rust prevention characteristics, thereby guaranteeing good protection against the effects of dirt and moisture. When Ceramic Grease is used, nuts and bolts are much easier to free afterwards.
Because the product is metal-free it also works as an insulator between different metals, thereby preventing corrosion.”
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Sorry, quick rant on PTFE/Teflon/polytetrafluoroethylene/polymer fume fever/Teflon Toxicosis look them up, are very bad environmentally, and to your health. https://www.ewg.org/research/canaries-kitchen
As to the comment that teflon tape isn't an electrical insulator since the cup threads cut through it, mechanically this may be correct. However, to have dissimilar metal corrosion, you also need an electrolyte, in this case water. The tape completely seals the threads from water incursion, which is why plumbers use it. So, no water, no corrosion.
#37
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Whenever we had a recurring squeaky-creaky situation the copper anti-sieze always solved it as some people have mentioned. With bb cartridges it was often standard practice to use anti sieze on the threads and on the inside of the cups rather than any type of grease. Again the copper did seem to work better.
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Yup. They're from the aeronautics industry where that is the standard for preventing galling. They used to recommend grease.
But quoting manufactures only gets you so far when you realize that companies to this day are making bikes that galvanically eat themselves. Most of the industry doesn't understand and/or care.
But quoting manufactures only gets you so far when you realize that companies to this day are making bikes that galvanically eat themselves. Most of the industry doesn't understand and/or care.
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It doesn't work that way. A coating of lube, no matter what's in it, is not going to prevent electrical contact between two pieces of metal threaded or pressed together. Antiseize works by preventing corrosion from filling all the gaps where the two pieces are not in direct contact - like the back side of the threads.
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Yup. They're from the aeronautics industry where that is the standard for preventing galling. They used to recommend grease.
But quoting manufactures only gets you so far when you realize that companies to this day are making bikes that galvanically eat themselves. Most of the industry doesn't understand and/or care.
But quoting manufactures only gets you so far when you realize that companies to this day are making bikes that galvanically eat themselves. Most of the industry doesn't understand and/or care.
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(NB: my newest bike is 10 years old, and none of my bikes has carbon fiber parts.)
Thanks!
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[QUOTE=HillRider;22860282]As long as we are off on this tangent, that article is not at all germain to bicycle use. If your bottom bracket ever exceeds 450ºF you have worse problems than just Teflon fume exposure.
I regularly reach such temperatures, I think you need to work on your cadence…….lol
I regularly reach such temperatures, I think you need to work on your cadence…….lol
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For general purposes regular Permatix Anti-Seize compound will work just fine. One jar is all ya need for life.
But is ya wanna get the real stuff for "Titanium" and "Titanium to Aluminum and steel" then ya need Mil-Spec Part Number: MIL-T-83483-1LB MOLY GRADE ANTI-SEIZE COMPOUND WITH MOLYBDENUM DISULFIDE. (Mil-Spec for Aircraft applications)
You can get a Generic 2oz jar on Amazon for about 20 USD (Not Bad!)
When you use Anti-Seize the right way ya use just very, very, little. But if ya see me coming in from the drive way with dark colored fingers and stains on my clothing and tools, then ya know I have been in the Anti-seize compound... Ha
My rule is that if ya have something that will come apart frequently then its Marine Grease. And if ya have something that is of dissimilar metals then its Anti-Seize compound.
Note: I have never worked on Titanium bicycles and all of the titanium devices I have worked on have had detailed lists of the POLs I could use.
But is ya wanna get the real stuff for "Titanium" and "Titanium to Aluminum and steel" then ya need Mil-Spec Part Number: MIL-T-83483-1LB MOLY GRADE ANTI-SEIZE COMPOUND WITH MOLYBDENUM DISULFIDE. (Mil-Spec for Aircraft applications)
You can get a Generic 2oz jar on Amazon for about 20 USD (Not Bad!)
When you use Anti-Seize the right way ya use just very, very, little. But if ya see me coming in from the drive way with dark colored fingers and stains on my clothing and tools, then ya know I have been in the Anti-seize compound... Ha
My rule is that if ya have something that will come apart frequently then its Marine Grease. And if ya have something that is of dissimilar metals then its Anti-Seize compound.
Note: I have never worked on Titanium bicycles and all of the titanium devices I have worked on have had detailed lists of the POLs I could use.
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Copper antiseize isn't bad, I'm saying that it isn't as ideal as other types because the biggest concern isn't galling. Other types would protect aluminum parts for longer in the wet. That's all.
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I don't understand this. None of my bikes appears to have any galvanic problems, which I assume are supposed to happen where two dissimilar metals meet. Can you explain this please?
(NB: my newest bike is 10 years old, and none of my bikes has carbon fiber parts.)
According to THIS, anti-seize contains solid particles (aluminum, nickel, copper, molybdenum disulfide, etc.) which prevent direct contact between fastener surfaces under load. This prevents galling. If it was merely to prevent corrosion, would not grease be equally effective?
Thanks!
(NB: my newest bike is 10 years old, and none of my bikes has carbon fiber parts.)
According to THIS, anti-seize contains solid particles (aluminum, nickel, copper, molybdenum disulfide, etc.) which prevent direct contact between fastener surfaces under load. This prevents galling. If it was merely to prevent corrosion, would not grease be equally effective?
Thanks!
Antiseize acts like little ball bearings, keeping galling metals from grinding into each other. But you can't expect that effect to electrically insulate the components, even with ceramic. There will be points of contact. And I'm not saying ceramic antiseize isn't a good idea, just that it isn't going to make the problem disappear.
Keep in mind that galvanic corrosion doesn't happen much toward the middle of the scale. Ti with steel, copper, brass or lead aren't going to react in big way at normal temperatures. Same with aluminum and steel. In bikes, the problem is Ti or carbon with aluminum. For a very long time there weren't any aluminum BB cups, so it was a non-issue.
If you're bike doesn't get wet much, you remove the components often, and the contact between surfaces is minimal - grease works fine. If you want more protection, use antiseize (the regular, cheap stuff works well). If you want the best antiseize, my opinion is that a sacrificial anode material (zinc or magnesium) might be the best protection for aluminum parts.
I use the cheap stuff on my several Ti bikes between pressed cups, seat posts and BB cups. I do worry sometimes about the aluminum shims Litespeed bonded into seat and headtubes on my old Obed, but so far, so good.
Last edited by Kontact; 04-16-23 at 12:43 PM.
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This is a Ti bike. From what I'm told by other sources as well, copper antiseize is better for Ti than aluminum antiseize.
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But if you read what I wrote, the recommendation for copper seems to come from industries that have more concerns about galling than Ti bicycles ever do. So I question spending extra money for special anti-galling copper antiseize when the cheaper aluminum/graphite/copper standard stuff may offer better anti-corrosion protection. But the best is likely something more reactive than aluminum, because we really aren't worried about hurting the Ti, but what the aluminum corroding and either sticking in the Ti or falling apart. This zinc antiseize specifically mentions acting as a sacrificial anode, like I mentioned:
- Resists seizing, galling, and cold welding, ******* galvanic action between dissimilar metals, Resists salt water corrosion
- ZINC ANTI-SEIZE does not separate It is non-dripping, non-hardening, permits easy disassembly and removal of connection even after lengthy service or severe conditions
- ZINC ANTI-SEIZE is recommended for aluminum and aluminum alloys It protects against corrosion through the anodic and electrochemical "Galvanizing" properties of the zinc dust
https://www.amazon.com/ZINC-ANTI-SEI...00JRT9L1Y?th=1
There is a great deal of hocus pocus in the bike business. It is not some spin-off of a very well engineered industry like aviation or automotive, but a group of largely well meaning amateurs that are making it up as they go along - borrowing what they can from other industries as appropriate. But there aren't any other industries that use materials, bearing, etc the way bikes use them. Everything on bikes are light, low RPM and designed for minimal drag. They aren't comparable to much of anything.
Last edited by Kontact; 04-15-23 at 10:08 PM.
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I know you are building a Ti bike. You already mentioned the Lynskey recommendation and copper is the usual recommendataion for screwing stuff into Ti.
But if you read what I wrote, the recommendation for copper seems to come from industries that have more concerns about galling than Ti bicycles ever do. So I question spending extra money for special anti-galling copper antiseize when the cheaper aluminum/graphite/copper standard stuff may offer better anti-corrosion protection. But the best is likely something more reactive than aluminum, because we really aren't worried about hurting the Ti, but what the aluminum corroding and either sticking in the Ti or falling apart. This zinc antiseize specifically mentions acting as a sacrificial anode, like I mentioned:
The forum blanked out R-E-T-A-R-D-S.
https://www.amazon.com/ZINC-ANTI-SEI...00JRT9L1Y?th=1
There is a great deal of hocus pocus in the bike business. It is not some spin-off of a very well engineered industry like aviation or automotive, but a group of largely well meaning amateurs that are making it up as they go along - borrowing what they can from other industries as appropriate. But there aren't any other industries that use materials, bearing, etc the way bikes use them. Everything on bikes are light, low RPM and designed for minimal drag. They aren't comparable to much of anything.
But if you read what I wrote, the recommendation for copper seems to come from industries that have more concerns about galling than Ti bicycles ever do. So I question spending extra money for special anti-galling copper antiseize when the cheaper aluminum/graphite/copper standard stuff may offer better anti-corrosion protection. But the best is likely something more reactive than aluminum, because we really aren't worried about hurting the Ti, but what the aluminum corroding and either sticking in the Ti or falling apart. This zinc antiseize specifically mentions acting as a sacrificial anode, like I mentioned:
The forum blanked out R-E-T-A-R-D-S.
https://www.amazon.com/ZINC-ANTI-SEI...00JRT9L1Y?th=1
There is a great deal of hocus pocus in the bike business. It is not some spin-off of a very well engineered industry like aviation or automotive, but a group of largely well meaning amateurs that are making it up as they go along - borrowing what they can from other industries as appropriate. But there aren't any other industries that use materials, bearing, etc the way bikes use them. Everything on bikes are light, low RPM and designed for minimal drag. They aren't comparable to much of anything.
Sacrificial anodes are an interesting topic. Of course , just like with water heaters, once the sacrificial anode has been totally eaten, you are no longer protected.