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Sodium Hydroxide to strip anodization off rims?

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Old 06-19-23, 02:37 AM
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Sodium Hydroxide to strip anodization off rims?

I know any removal of anodization will late a layer of material with it, but will the lye weaken the rim in any other way? I'm mainly worried about chemical reaction.
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Old 06-19-23, 07:28 AM
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Sodium Hydroxide is what is used to strip off anodized car mags and motorcycle parts, so would also apply to your rims.

It might be a good idea to strip the wheel down to just the rim, hub and spokes removed.
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Old 06-19-23, 07:34 AM
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Originally Posted by trashbiker
I know any removal of anodization will late a layer of material with it, but will the lye weaken the rim in any other way? I'm mainly worried about chemical reaction.
Lye will eat anything right up to and including dental fillings. It is an alkali. I've used t a lot to remove ugly anno before polishing. After using, make sure you neutralize the lye before proceeding. Vinegar in a spray bottle followed with water works.
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Old 06-19-23, 08:31 AM
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Having seen a number of home stripped anodizing results I will only add that don't be surprised if the rim looks pretty bad after. If the rim has eyelets take a lot of care rinsing the lye off there. Andy
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Old 06-19-23, 08:46 AM
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Originally Posted by Andrew R Stewart
Having seen a number of home stripped anodizing results I will only add that don't be surprised if the rim looks pretty bad after. If the rim has eyelets take a lot of care rinsing the lye off there. Andy
Sodium hydroxide is more highly reactive with the aluminum than with the aluminum oxide layer that makes up the anodized surface. That is likely the cause of the poor results. Because of the higher reaction rate for aluminum, I would also be dubious about the strength of a thin aluminum part like a rim following treatment. There is no way to preferentially control the reaction.
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Old 06-19-23, 09:00 AM
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Originally Posted by cyccommute
Sodium hydroxide is more highly reactive with the aluminum than with the aluminum oxide layer that makes up the anodized surface. That is likely the cause of the poor results. Because of the higher reaction rate for aluminum, I would also be dubious about the strength of a thin aluminum part like a rim following treatment. There is no way to preferentially control the reaction.
Been doing this since the 70's. Done 15 or 20 rims with no issue.
Garbage bag and oven cleaner were the method used. Oven cleaner is lye based but not pure lye. Does the job without the scars of leaving it in too long. If you don't neutralize the lye, it will keep eating.
Your mileage may vary.

The wheel has to be dissembled.
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Old 06-19-23, 09:11 AM
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Originally Posted by Schweinhund
Been doing this since the 70's. Done 15 or 20 rims with no issue.
Garbage bag and oven cleaner were the method used. Oven cleaner is lye based but not pure lye. Does the job without the scars of leaving it in too long. If you don't neutralize the lye, it will keep eating.
Your mileage may vary.

The wheel has to be dissembled.
The real question is why do you keep buying anodized rims? Lots of rims out there that aren’t anodized.

As to the process, no matter what the concentration of sodium hydroxide, it will react with the aluminum more readily and at a higher rate than with the aluminum oxide. The result will be an unknown change in the structure of the rim. Further, sodium hydroxide may not even be removing the anodized layer since conditions to form the sodium aluminate are quite severe. It’s more likely that the dye used on anodized rims is being decolored rather than the anodized layer is being removed.
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Old 06-19-23, 09:29 AM
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Originally Posted by cyccommute
The real question is why do you keep buying anodized rims? Lots of rims out there that aren’t anodized.

As to the process, no matter what the concentration of sodium hydroxide, it will react with the aluminum more readily and at a higher rate than with the aluminum oxide. The result will be an unknown change in the structure of the rim. Further, sodium hydroxide may not even be removing the anodized layer since conditions to form the sodium aluminate are quite severe. It’s more likely that the dye used on anodized rims is being decolored rather than the anodized layer is being removed.
I am wondering that as well? You can get some excellent rims in raw or various anodizations or polished (or both) or painted from Velocity not sure why the need for harsh chemicals? I mean I have never had an issue finding a rim that will look good on a bike I am building there are so many options and some cheaper and some more expensive but there is always been something.
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Old 06-19-23, 09:32 AM
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Originally Posted by cyccommute
The real question is why do you keep buying anodized rims? Lots of rims out there that aren’t anodized.

As to the process, no matter what the concentration of sodium hydroxide, it will react with the aluminum more readily and at a higher rate than with the aluminum oxide. The result will be an unknown change in the structure of the rim. Further, sodium hydroxide may not even be removing the anodized layer since conditions to form the sodium aluminate are quite severe. It’s more likely that the dye used on anodized rims is being decolored rather than the anodized layer is being removed.
This is true.
It was mostly for friends. When you can get one blue outer and one green one, you make them both shiny.
Other times it was when could get one dark anno and one something else. mostly from need
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Old 06-19-23, 09:38 AM
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I have an experiment going now. hard anno matrix in a clear bag doused in oven cleaner.
I'll check it in a couple of hours.
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Old 06-19-23, 09:54 AM
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Originally Posted by cyccommute
no matter what the concentration of sodium hydroxide, it will react with the aluminum more readily and at a higher rate than with the aluminum oxide.
It is almost as if they anodize aluminum to make the surface less reactive.
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Old 06-19-23, 10:00 AM
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I ruined a centrifuge rotor (by accident) with a sodium hydroxide spill. I wouldn't take a chance on wheels I cared about (which is any wheel that I would ride).
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Old 06-19-23, 10:14 AM
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Originally Posted by Schweinhund
If you don't neutralize the lye, it will keep eating.
It might seem that it keeps going, but the reaction will stop when all of one (or more) of the reactants has been consumed. The limiting factor is probably the NaOH.
Here's the reaction for aluminum and sodium hydroxide:
2NaOH+2Al+2H2O2NaAlO2+2H2
Notice that one of the products is hydrogen gas... maybe enough to burn.
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Old 06-19-23, 10:27 AM
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Originally Posted by Schweinhund
I have an experiment going now. hard anno matrix in a clear bag doused in oven cleaner.
I'll check it in a couple of hours.
Just checked it, it's starting to go...
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Old 06-19-23, 10:29 AM
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Originally Posted by sweeks
It might seem that it keeps going, but the reaction will stop when all of one (or more) of the reactants has been consumed. The limiting factor is probably the NaOH.
Here's the reaction for aluminum and sodium hydroxide:
2NaOH+2Al+2H2O2NaAlO2+2H2
Notice that one of the products is hydrogen gas... maybe enough to burn.
Didn't know that, but that's not the reason I do it outside. It's a good reason to keep doing it outside though.
Thank you for the heads up.
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Old 06-19-23, 10:33 AM
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Originally Posted by sweeks
It might seem that it keeps going, but the reaction will stop when all of one
You mean eventually. It will keep eating because you will always use more than you need.
You will need to stop the reaction when your needs are complete.
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Old 06-19-23, 12:22 PM
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Ok, so here goes.
Best guess is give it about 3 hours with the oven cleaner and I could polish this thing in an hour or so including sanding.

wheel is a matrox 550 out of the bin

wheel

wjeel with 1 minute of sanding with 1500 grit and no oven cleaner

2 hours in oven cleaner and about 1 minute with 1500grit


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